2013年2月25日 · The thermodynamic modelling of the Si–Ta system is made with the CALPHAD method. The liquid and bcc phases are treated with a solution model and compounds as stoichiometric. The excess Gibbs energy of the solution phases is assessed with the T dependence by Kaptay. The calculations based on the …

Calculated phase diagram for the system Si-Ta. The Si-Ta system has been assessed by [89Vah] and it was later revised by [03Che]. The phase diagram presents complete mutual solubility in the liquid state, a negligible solubility of Ta in crystalline Si, and of Si in bcc-Ta.

2009年9月18日 · The assessed thermodynamic descriptions of the Si-Ta and Si-W binary systems will serve as part of the thermodynamic database for the Si-C-M (M: Ta and W) alloys. The knowledge of phase diagram and thermodynamic properties of the Si-Ta and Si-W systems is of technical importance for metallic contacts between Ta, W, a

以2000 K下相似Si-过渡金属体系中液体的混合焓进行比较，以判断计算的合理性。 Si-Ta 和 Si-W 二元系统的评估热力学描述将作为 Si-CM（M：Ta 和 W）合金热力学数据库的一部分。

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The phase diagram and thermodynamic properties of the Si-Ta and Si-W systems were assessed using the CALPHAD approach with available experimental dat...

2013年2月25日 · The thermodynamic modeling of the silicon–tantalum binary system was carried out with the help of the CALPHAD (CALculation of PHAse Diagram) method. A solution model was used for the description of the liquid and bcc phases while the Si 2 Ta, Si 3 Ta 5 _LT, Si 3 Ta 5 _HT SiTa 2 and SiTa 3 compounds are treated as