
MOF-derived FeF2 nanoparticles@graphitic carbon undergoing in …
2020年11月5日 · FeF 2 nanoparticles embedded with graphitic carbon were successfully synthesized using Fe-MIL-88B. The FeF 2 @GC electrode shows improved discharge capacity, stable retention, and high rate performance in SIBs. The phase transformation of FeF 2 to FeF 3 during cycles is an essential factor for the high electrochemical performance.
Interface engineering of FeOF/FeF2 heterostructure for ultrastable …
2024年2月1日 · Thermogravimetry analysis (TGA, STA-449-F3) was tested under an air atmosphere with a heating rate of 10 °C/min and a temperature range from 50 to 800 °C. The ultraviolet–visible–near infrared (UV–Vis–NIR) absorption spectra of all samples were measured on a UV–Vis–NIR spectrophotometer (Lambda 750, PerkinElmer).
Enabling Long Cycle Life and High Rate Iron Difluoride Based …
2022年5月14日 · Advanced electron microscopy reveals that the in situ formation of stable Fe 3 O 4 layers on the surface of FeF 2 prevents the electrolyte decomposition and leaching of iron (Fe), thus enhancing the cyclability.
黄俏副教授, 黄建宇教授Advanced Science:正极表面原位修饰实 …
通过将纳米fef2嵌入到聚合物衍生碳基体(pdc)中,形成具有稳定离子电导和电子电导的fef2@pdc复合材料,实现了前所未有的超长循环寿命以及高倍率性能。
Figure S1. Thermogravimetric analysis (TGA) of HTB-FeF2.2(OH)0.8
Thermogravimetric analysis (TGA) of HTB-FeF2.2(OH)0.8 · (H2O)0.33 performed under He up to 350°C. The end product was analyzed by XRD and Mössbauer spectroscopy (Fig. 9).
Improved reversibility of phase transformations using electron-rich ...
2022年4月15日 · Iron difluoride (FeF 2) is considered as a promising conversion-typed cathode material in SIBs because of its low-cost and high theoretical capacity of 571 mAh g −1. Additionally, storing larger sodium ions is more suitable in conversion type cathode when compared to other insertion-typed cathodes in SIBs.
Rational design of FeF2‐based cathode to realize …
2024年9月29日 · Figure 2G shows the thermogravimetric analysis (TGA) profiles of bare FeF 2 (a) and FeF 2 @CNTs (b), which suggest a weight loss of 3.1 wt.% for bare FeF 2 between 20°C and 200°C, mainly attributed to surface water evaporation.
TGA under a humid air atmosphere of Fe 2 F 5 (Htaz) (3).
We combine powder neutron diffraction, magnetometry and ⁵⁷ Fe Mössbauer spectrometry to determine the nuclear and magnetic structures of a strongly interacting weberite-type inorganic–organic...
Nanoparticulate FeF2@C as a Li Battery Conversion Cathode
2022年10月28日 · In this work, we report a simple synthesis to produce crystalline FeF 2 particles approximately 35 nm in diameter surrounded by a thin carbon shell (FeF 2 @C) and demonstrate its excellent performance as a cathode in Li metal batteries.
黄建宇团队EnSM:表面工程实现无粘结剂高性能FeF2正极基全电 …
结果表明,裸漏的FeF2电极循环性能随着电解液负载量的降低,性能显著降低,在贫电解液(5uL/mg)条件下,几乎没有,30圈后,几乎没有容量,而FeF2-cPAN电极即使在贫电解液循环150圈,容量依然保持320mAh/g。
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