2005年6月25日 · Scanning tunneling microscopy (STM) measurements of compound 2 inserted into a SAM of C11 thiol reveal that molecule 2 exhibits (i) the stochastic switching characteristic of wire molecules embedded in insulating SAMs and (ii) higher conductivity than the C11 thiol SAM.

1992年7月15日 · Syntheses of the Ru2 compounds I and 2 In the synthesis of the dinuclear Ru complexes, RuCl3, 3H20, Ru2(OAc)4 and Ru2(OAc)4Cl have been the most commonly used starting materials [4, 28]. However, in our preparative work K3[Ru2(CO3)4]- 4H20 has proven to be another valuable starting material.

本文围绕着此热点领域，以K[Ru（Hedm）O]和cis－Ru（DMSO）4C12以及. 中7个配合物的单晶结构。 使用元素分析、红外光谱、电子光谱等手段对配合物. 究。 三核Ru（Ⅲ）配合物的晶体结构。 研究了4，4’．联吡啶桥联双核钌配合物的磁学性. 质。 个新型Ru（II）．多酸配合物，解析了它的晶体结构。 同pH值条件下的电子光谱进行了研究。 4．用电子光谱和荧光淬灭等方法初步研究了这9个配合物与DNA的作用。 hasbeenstudied．. methods．. and瓜．. …

2005年11月1日 · Reported herein are the synthesis, electrochemical and structural characterization of wire-like Ru 2-alkynyl compounds, Ru 2 (ap) 4 (Ln) x, where ap is 2-anilinopyridinate, and Ln is –(C CC 6 H 4) n SCH 2 CH 2 SiMe 3 with n = 1 (1) and 2 (2), and x can be 1 (a) and 2 (b).

Effect of Axial Ligands on the Oxidation State, Structure, and Electronic Configuration of Diruthenium Complexes. Synthesis and Characterization of Ru2(dpf)4Cl, Ru2(dpf)4(C⋮CC6H5), Ru2(dpf)4(C⋮CC6H5)2, and Ru2(dpf)4(CN)2 (dpf = N,N‘-Diphenylformamidinate). Inorganic Chemistry 1996, 35 (10) , 3012-3021.

2019年9月15日 · Two diruthenium (I) complexes with di (pyridyl)pyrrolide ligands were synthesized by oxidation or reduction method. The bonding flexibility of di (pyridyl)pyrrolide ligand leads versatile coordination modes. [Ru 2 (CO) 4] 2+ complexes with di (pyridyl)pyrrolide ligands display ligand-centred and Ru-centred redox processes.

2005年7月1日 · 本贡献报告了线状 Ru2(ap)4(OPEn) 的合成、表征和电荷传输特性，其中 ap 是 2-苯胺吡啶酸盐，OPE 是 -(C⋮CC6H4)nSCH2CH2SiMe3，n = 1 (1)和 2 (2)。 插入到 C11 硫醇 SAM 中的化合物 2 的扫描隧道显微镜 (STM) 测量表明，分子 2 表现出 (i) 嵌入绝缘 SAM 中的线分子的随机开关特性和 ...

2005年5月24日 · Two series of Ru2-capped oligoynes, Ru2(ap)4(C2kY) (ap = 2-anilinopyridinate, k = 2−5, Y = SiiPr3 and Ph), were obtained from the reactions between Ru2(ap)4(C2(k-1)H) and ethynes HC⋮CY under Hay conditions, and their electronic and optical properties as a function of the number of C⋮C bonds were explored.

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2015年8月3日 · Reported in this Article are the preparation and characterization of a series of new Ru2 (II,III) compounds bearing one cross-conjugated σ-geminal-diethynylethene ligand (gem-DEE), namely, Ru2 (Xap)4 (Y-gem-DEE) (Xap = N,N'-anilinopyridinate (ap) or 2- (3,5-dimethoxy)anilinopyridinate (DiMeOap), and Y = Si (i)Pr3 (1) or H (2)) and [Ru2 (ap)4]2 (...