The tert-butoxycarbonyl group is used to protect the amino group of amino acids during the Merrifield solid phase peptide synthesis procedure The group is then removed by treatment with anhydrous acid. The mechanism of addition and removal is as follows:The amino acid under basic conditions reacts with di-tert-butyl dicarbonate to give tetrahedral intermediate I; 2. collapse of the tetrahedral intermediate gives the BOC-aa; 3. in the removal sequence, protonation from anhydrous acid gives proton
The tert-butoxycarbonyl group is used to protect the amino group of amino acids during the Merrifield solid phase peptide synthesis procedure The group is then removed by treatment
VIDEO ANSWER: Thank you students. I will explain to you the question. He had a question in this question. Merrifield Merrifield solid Face solid phase peptide …
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PPT - Solid-Phase Peptide Synthesis: The Merrifield Method PowerPoint Presentation - ID:3263572
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SOLVED: The tert-butoxycarbonyl group is used to protect the amino group of amino acids during the Merrifield solid phase peptide synthesis procedure. The group is then removed by treatment with anhydrous acid. The mechanism of addition and removal is as follows:The amino acid under basic conditions reacts with di-tert-butyl dicarbonate to give a tetrahedral intermediate. Collapse of the tetrahedral intermediate gives the BOC-aa. In the removal sequence, protonation from anhydrous acid gives pro
SOLVED: The tert-butoxycarbonyl group is used to protect the amino group of amino acids during the Merrifield solid phase peptide synthesis procedure. The group is then removed by treatment with anhydrous acid. The mechanism of addition and removal is as follows:The amino acid under basic conditions reacts with di-tert-butyl dicarbonate to give a tetrahedral intermediate. Collapse of the tetrahedral intermediate gives the BOC-aa. In the removal sequence, protonation from anhydrous acid gives pro
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