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The deuterium kinetic isotope effect for the halogenation of an a... | Channels for Pearson

SOLVED: Predict whether a normal or inverse kinetic deuterium isotope effect will be observed in each of the following reactions. Indicate any reaction in which you would expect kHI/kD to be greater than [WO]. Justify each answer with a transition state structure. The isotopically-substituted hydrogens are indicated as follows: a) Ph CH2CH2NH2 b) Ph CH2CH2OH c) Ph CH = CH2 d) Ph CH = C2H5

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